The Vitrification reference article from the English Wikipedia on 24-Apr-2004
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Vitrification

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By contrast with freezing, which produces crystallization and other structural alterations, vitrification cools substances to form a glass without disturbing their structure.

In the context of Cryonics, Vitrification is intended to fully maintain the information encoded in the patient's brain. Early cryonicists were frozen rather than vitrified, leading to crystalization of water within the cells. This crystalization often leads to shards of ice which damages cells.