Ostwald process
The
Ostwald process is a
commercial process, invented by
Wilhelm Ostwald, used to produce
nitric acid. Following production from the
Haber process,
Ammonia is heated with a catalyst (
platinum) to form
nitric oxide that is then
oxidized to yield
nitrogen dioxide, which in turn reacts with
water to yield nitric acid and nitric oxide:
- 4 NH3 + 5 O2 → 4 NO + 6 H2O
- 2 NO + O2 → 2 NO2
- 4 NO2 + O2 + 2 H2O → 4 HNO3(aq)
Fixing
Nitrogen into ammonia and nitric acid was a key development in the production of fertilisers and
explosives. Previously sources of Nitrogen had been
Guano and
Chile saltpeter (NaNO3).